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Conformational landscape of the SF6 dimer as revealed by various free jet conditions

Abstract : The experiment SPIRALES coupling a tunable infrared laser to a pulsed supersonic free jet has allowed us to reinvestigate the high-resolution absorption spectroscopy of the SF 6 dimer in the ν3 mode region under various experimental conditions: In addition to the SF 6 dimer spectrum so far reported, we demonstrate the existence of two new spectral features : i) one assigned to a second conformer of this species, characterized by a larger interatomic distance as well as ii) a complex (SF 6) 2-He.
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https://hal.archives-ouvertes.fr/hal-02344573
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Submitted on : Monday, November 4, 2019 - 11:13:10 AM
Last modification on : Friday, March 5, 2021 - 3:11:27 PM
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M. Gaveau, M. Mons, L. Bruel, A. Potapov, A. Turner, et al.. Conformational landscape of the SF6 dimer as revealed by various free jet conditions. 31ST INTERNATIONAL SYMPOSIUM ON RAREFIED GAS DYNAMICS: RGD31, Jul 2018, Glasgow, France. pp.030004, ⟨10.1063/1.5119529⟩. ⟨hal-02344573⟩

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