Phosphorus-free nitrogen-containing catalytic systems for hydroformylation and tandem hydroformylation-based reactions

D.N. Gorbunov (1) , M.V. Nenasheva (1) , M.V. Terenina (1) , Yu.S Kardasheva (1) , E.R. Naranov (2) , A.L. Bugaev (3) , A.V. Soldatov (3) , A.L. Maximov (2) , Sébastien Tilloy (4) , Eric Monflier (4) , E.A. Karakhanov (1)

1 Moscow State University
2 TIPS - A.V. Topchiev Institute of Petrochemical Synthesis
3 SFEDU - Southern Federal University [Rostov-on-Don]
4 UCCS Équipe Catalyse Supramoléculaire

Hydroformylation is an important industrial process applied for the production of many highly-demanded chemicals. For now, only the Co/phosphine, Rh/phosphine, or ligand-free systems are used in industry. Although most of the research dealing with hydroformylation also considers systems with phosphorus-containing ligands or heterogeneous materials, the interest in developing phosphorus-free nitrogen-containing systems tends to grow during the last decade. N-ligands can be easier to synthesize, more stable towards oxidation, and at the same time add some useful features, such as the higher activity in the tandem hydroformylation-based reactions. The review is focused on the progress made in the design of N-ligands for homogeneous and biphasic hydroformylation of unsaturated compounds, as well as N-containing heterogeneous catalysts for the process. In addition, the data on tandem reactions, such as reductive hydroformylation and hydroaminomethylation, are systematized and discussed.

Mots clés: Hydroformylation; Nitrogen-containing; ligands; Tandem reactions

Domaines: Chimie; Catalyse

D.N. Gorbunov, M.V. Nenasheva, M.V. Terenina, Yu.S Kardasheva, E.R. Naranov, et al.. Phosphorus-free nitrogen-containing catalytic systems for hydroformylation and tandem hydroformylation-based reactions. Applied Catalysis A : General, 2022, 647 (20), pp.118891. ⟨10.1016/j.apcata.2022.118891⟩. ⟨hal-03829262⟩